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Vinaginsenoside R8 has the side chain with a migrated double bond on introduction of OH at C-25. Most of the known saponins have been isolated from other Panax spp., though gypenoside XVII and hemsloside Ma3 were not previously isolated from Araliaceae but from Cucurbitaceous plants. www.bocsci.com/vinaginsenoside-r8-cas-156042-22-7-item-479857.html

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